Make every green pixel in the input image transparent:

ffmpeg -i input.png -vf chromakey=green out.png

Overlay a greenscreen-video on top of a static black background.

ffmpeg -f lavfi -i color=c=black:s=1280x720 -i video.mp4 -shortest -filter_complex "[1:v]chromakey=0x70de77:0.1:0.2[ckout];[0:v][ckout]overlay[out]" -map "[out]" output.mkv