Make every green pixel in the input image transparent:

ffmpeg -i input.png -vf colorkey=green out.png

Overlay a greenscreen-video on top of a static background image.

ffmpeg -i background.png -i video.mp4 -filter_complex "[1:v]colorkey=0x3BBD1E:0.3:0.2[ckout];[0:v][ckout]overlay[out]" -map "[out]" output.flv